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Bis{2,2'-[methyl-aza-nediylbis(methyl-ene)]bis-(4,6-dimethyl-phenolato)-?(3) O,N,O'}titanium(IV) toluene sesquisolvate.

ABSTRACT: The title compound, [Ti(C19H23NO2)2]·1.5C7H8, crystallizes with one titanium complex mol-ecule per asymmetric unit together with one and a half toluene mol-ecules. The Ti(IV) atom is coordinated by two fully deprotonated O,N,O'-tridentate phen-oxy-amine ligands in a distorted octa-hedral environment. Within this arrangement the O atoms occupy the equatorial sites and the N atoms the axial sites. One of the toluene mol-ecules is disordered over two sets of sites in a 0.628?(18):0.372?(18) ratio.

SUBMITTER: Chung Y 

PROVIDER: S-EPMC3629497 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Bis{2,2'-[methyl-aza-nediylbis(methyl-ene)]bis-(4,6-dimethyl-phenolato)-κ(3) O,N,O'}titanium(IV) toluene sesquisolvate.

Chung Yongseog Y   Kim Youngjo Y  

Acta crystallographica. Section E, Structure reports online 20130320 Pt 4

The title compound, [Ti(C19H23NO2)2]·1.5C7H8, crystallizes with one titanium complex mol-ecule per asymmetric unit together with one and a half toluene mol-ecules. The Ti(IV) atom is coordinated by two fully deprotonated O,N,O'-tridentate phen-oxy-amine ligands in a distorted octa-hedral environment. Within this arrangement the O atoms occupy the equatorial sites and the N atoms the axial sites. One of the toluene mol-ecules is disordered over two sets of sites in a 0.628 (18):0.372 (18) ratio. ...[more]

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