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{2,7-Dieth-oxy-8-[(naphthalen-1-yl)carbon-yl]naph-thalen-1-yl}(naphthalen-1-yl)methanone.


ABSTRACT: In the title compound, C36H28O4, the 1-naphthoyl groups at the 1- and 8-positions of the central 2,7-dieth-oxy-naphthalene ring system are aligned almost anti-parallel and make a dihedral angle of 76.59?(4)°. The dihedral angles between the central 2,7-dieth-oxy-naphthalene ring system and the terminal naphthalene ring systems are 86.48?(4) and 83.97?(4)°. In the crystal, C-H?? inter-actions between the central naphthalene ring systems and the naphthoyl groups are observed along the a axis, with the mol-ecules forming a columnar structure. The columns are linked into chains parallel to the b axis by C-H?O inter-actions.

SUBMITTER: Tsumuki T 

PROVIDER: S-EPMC3629527 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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{2,7-Dieth-oxy-8-[(naphthalen-1-yl)carbon-yl]naph-thalen-1-yl}(naphthalen-1-yl)methanone.

Tsumuki Takehiro T   Takeuchi Ryo R   Kawano Hiroyuki H   Yonezawa Noriyuki N   Okamoto Akiko A  

Acta crystallographica. Section E, Structure reports online 20130306 Pt 4


In the title compound, C36H28O4, the 1-naphthoyl groups at the 1- and 8-positions of the central 2,7-dieth-oxy-naphthalene ring system are aligned almost anti-parallel and make a dihedral angle of 76.59 (4)°. The dihedral angles between the central 2,7-dieth-oxy-naphthalene ring system and the terminal naphthalene ring systems are 86.48 (4) and 83.97 (4)°. In the crystal, C-H⋯π inter-actions between the central naphthalene ring systems and the naphthoyl groups are observed along the a axis, with  ...[more]

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