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N-Cyclo-hexyl-3-methyl-benzamidine.

ABSTRACT: The title amidine compound, C14H20N2, prepared by a one-pot reaction, is asymmetric as only one N atom has an alkyl substituent. The terminal cyclo-hexyl group connected to the amino N atom is located on the other side of the N-C-N skeleton to the 4-methylbenzene ring and has a chair conformation. The dihedral angle between the phenyl ring and the NCN plane is 47.87?(12)°. In the crystal, mol-ecules are linked via N-H?N hydrogen bonds, forming chains propagating along the a-axis direction.

SUBMITTER: Liu RQ

PROVIDER: S-EPMC3629577 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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N-Cyclo-hexyl-3-methyl-benzamidine.

Liu Rui-Qin RQ Bai Sheng-Di SD Wang Tao T

Acta crystallographica. Section E, Structure reports online 20130309 Pt 4

The title amidine compound, C14H20N2, prepared by a one-pot reaction, is asymmetric as only one N atom has an alkyl substituent. The terminal cyclo-hexyl group connected to the amino N atom is located on the other side of the N-C-N skeleton to the 4-methylbenzene ring and has a chair conformation. The dihedral angle between the phenyl ring and the NCN plane is 47.87 (12)°. In the crystal, mol-ecules are linked via N-H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. ...[more]

PMID: 23634064

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