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(1R,2S,5R)-(-)-Menthyl (S)-2-(methoxy-carbonyl)-benzene-sulfinate.

ABSTRACT: In the title chiral sulfinic acid ester, C18H26O4S, the cyclo-hexane ring of the menthyl fragment adopts a chair conformation. The mol-ecular shape is defined by the dihedral angle of 47.87?(8)° between the mean planes of the cyclo-hexane and benzene rings. In the crystal, mol-ecules related by the screw axis are connected into chains along [010] by weak Car-H?O=S contacts.

SUBMITTER: Altamura M

PROVIDER: S-EPMC3648263 | biostudies-literature | 2013 May

REPOSITORIES: biostudies-literature

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(1R,2S,5R)-(-)-Menthyl (S)-2-(methoxy-carbonyl)-benzene-sulfinate.

Altamura Maria M Guidi Antonio A Jierry Loic L Paoli Paola P Rossi Patrizia P

Acta crystallographica. Section E, Structure reports online 20130413 Pt 5

In the title chiral sulfinic acid ester, C18H26O4S, the cyclo-hexane ring of the menthyl fragment adopts a chair conformation. The mol-ecular shape is defined by the dihedral angle of 47.87 (8)° between the mean planes of the cyclo-hexane and benzene rings. In the crystal, mol-ecules related by the screw axis are connected into chains along [010] by weak Car-H⋯O=S contacts. ...[more]

PMID: 23723883

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