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Influence of material transition and interfacial area changes on flow and concentration in electro-osmotic flows.


ABSTRACT: This paper presents a numerical study to investigate the effect of geometrical and material transition on the flow and progression of a sample plug in electrokinetic flows. Three cases were investigated: (a) effect of sudden cross-sectional area change (geometrical transition or mismatch) at the interface, (b) effect of only material transition (i.e. varying ?-potential), and (c) effect of combined material transition and cross-sectional area change at the interface. The geometric transition was quantified based on the ratio of reduced flow area A2 at the mismatch plane to the original cross-sectional area A1. Multiple simulations were performed for varying degrees of area reduction i.e. 0-75% reduction in the available flow area, and the effect of dispersion on the sample plug was quantified by standard metrics. Simulations showed that a 13% combined material and geometrical transition can be tolerated without significant loss of sample resolution. A 6.54% reduction in the flow rates was found between 0% and 75% combined material and geometrical transition.

SUBMITTER: Rani SD 

PROVIDER: S-EPMC3653442 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Influence of material transition and interfacial area changes on flow and concentration in electro-osmotic flows.

Rani Sudheer D SD   You Byoung-Hee BH   Soper Steve A SA   Murphy Michael C MC   Nikitopoulos Dimitris E DE  

Analytica chimica acta 20130204


This paper presents a numerical study to investigate the effect of geometrical and material transition on the flow and progression of a sample plug in electrokinetic flows. Three cases were investigated: (a) effect of sudden cross-sectional area change (geometrical transition or mismatch) at the interface, (b) effect of only material transition (i.e. varying ζ-potential), and (c) effect of combined material transition and cross-sectional area change at the interface. The geometric transition was  ...[more]

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