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Silica encapsulation of thiol-stabilized lead selenide (PbSe) quantum dots in aqueous solution.

ABSTRACT: Silica encapsulation of lead selenide quantum dots (PbSe QDs) in aqueous solution is reported. Thioglycolic acid (TGA) stabilized PbSe QDs were modified with 3-mercaptopropyl trimethoxysilane (MPS) through vigorous stirring in water for 18-24 h in alkaline solution (pH 10.4-10.6). Silica shell was developed by controlled deposition and precipitation of silicates from sodium silicate solution onto MPS modified QDs surfaces. TEM images showed multiple PbSe QDs encapsulated in silica shell. The size of PbSe-SiO2 core-shell nanocrystals was estimated to be 25-30 nm by TEM. Elemental compositions (Pb, Se and Si) were investigated by EDX analysis. The purified colloids of PbSe-SiO2 QDs were stable for months when kept at 4 °C.

SUBMITTER: Primera-Pedrozo OM

PROVIDER: S-EPMC3665949 | biostudies-literature | 2013 Jul

REPOSITORIES: biostudies-literature

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Silica encapsulation of thiol-stabilized lead selenide (PbSe) quantum dots in aqueous solution.

Primera-Pedrozo Oliva M OM Ates Mehmet M Arslan Zikri Z

Materials letters 20130701

Silica encapsulation of lead selenide quantum dots (PbSe QDs) in aqueous solution is reported. Thioglycolic acid (TGA) stabilized PbSe QDs were modified with 3-mercaptopropyl trimethoxysilane (MPS) through vigorous stirring in water for 18-24 h in alkaline solution (pH 10.4-10.6). Silica shell was developed by controlled deposition and precipitation of silicates from sodium silicate solution onto MPS modified QDs surfaces. TEM images showed multiple PbSe QDs encapsulated in silica shell. The siz ...[more]

PMID: 23729944

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