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Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones.

ABSTRACT: A combined experimental and computational study on regioselective gold-catalyzed synthetic routes to 1,3-oxazinan-2-ones (kinetically controlled products) and 1,3-oxazin-2-one derivatives (thermodynamically favored) from easily accessible allenic carbamates has been carried out.

SUBMITTER: Alcaide B 

PROVIDER: S-EPMC3678844 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones.

Alcaide Benito B   Almendros Pedro P   Quirós M Teresa MT   Fernández Israel I  

Beilstein journal of organic chemistry 20130426

A combined experimental and computational study on regioselective gold-catalyzed synthetic routes to 1,3-oxazinan-2-ones (kinetically controlled products) and 1,3-oxazin-2-one derivatives (thermodynamically favored) from easily accessible allenic carbamates has been carried out. ...[more]

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