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9-[3-(Carbazol-9-yl)-5-methyl-phen-yl]carbazole.

ABSTRACT: The title compound, C31H22N2, crystallizes with two symmetry-independent mol-ecules in the asymmetric unit. The mol-ecules have slightly different conformations, the dihedral angles between the central phenyl ring and the carbazolyl groups being 56.29?(4) and 59.57?(4)° in one mol-ecule and 48.71?(4) and 65.47?(4)° in the other. In the crystal, mol-ecules are linked by weak C-H?? and ?-? [centroid-centroid distances = 3.7698?(10), 3.8292?(9), 3.9429?(10) and 3.9431?(10)?Å].

SUBMITTER: Kim JE

PROVIDER: S-EPMC3684916 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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9-[3-(Carbazol-9-yl)-5-methyl-phen-yl]carbazole.

Kim Jae Eun JE Kim Jun Hee JH Sim Wonbo W Lee Jai Young JY

Acta crystallographica. Section E, Structure reports online 20130504 Pt 6

The title compound, C31H22N2, crystallizes with two symmetry-independent mol-ecules in the asymmetric unit. The mol-ecules have slightly different conformations, the dihedral angles between the central phenyl ring and the carbazolyl groups being 56.29 (4) and 59.57 (4)° in one mol-ecule and 48.71 (4) and 65.47 (4)° in the other. In the crystal, mol-ecules are linked by weak C-H⋯π and π-π [centroid-centroid distances = 3.7698 (10), 3.8292 (9), 3.9429 (10) and 3.9431 (10) Å]. ...[more]

PMID: 23795018

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