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2-(4-Chloro-phen-yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole.

ABSTRACT: The title compound, C24H19ClN2, crystallizes with two independent mol-ecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two mol-ecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06?(8), 5.61?(8) and 41.09?(8)°, respectively, with the imadazole ring in one mol-ecule and 71.53?(8), 28.85?(8) and 41.87?(8)°, respectively, in the other. The crystal structure features C-H?? inter-actions and weak ?-? stacking inter-actions [centroid-centroid distances = 3.6937?(10) and 4.0232?(10)?Å] between the chloro-phenyl rings, which form a three-dimensional supramolecular structure.

SUBMITTER: Mohamed SK 

PROVIDER: S-EPMC3685034 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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2-(4-Chloro-phen-yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole.

Mohamed Shaaban K SK   Akkurt Mehmet M   Marzouk Adel A E AA   Santoyo-Gonzalez Francisco F   Elremaily Mahmoud A A MA  

Acta crystallographica. Section E, Structure reports online 20130511 Pt 6

The title compound, C24H19ClN2, crystallizes with two independent mol-ecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two mol-ecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06 (8), 5.61 (8) and 41.09 (8)°, respectively, with the imadazole ring in one mol-ecule and 71.53 (8), 28.85 (8) and 41.87 (8)°, respectively, in the other. The crystal structure features C-H⋯π inter-actions and  ...[more]

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