6-(4-Methyl-phen-yl)-1,3,5-triazine-2,4-di-amine-benzoic acid (1/1).

ABSTRACT: The benzoic acid mol-ecule of the title adduct, C10H11N5·C7H6O2, is approximately planar, with a dihedral angle of 7.2?(3)° between the carb-oxy-lic acid group and the benzene ring. In the triazine mol-ecule, the plane of the triazine ring makes a dihedral angle of 28.85?(9)° with that of the adjacent benzene ring. In the crystal, the two components are linked by N-H?O and O-H?N hydrogen bonds with an R 2 (2)(8) motif, thus generating a 1 + 1 unit of triazine and benzoic acid mol-ecules. The acid-base units are further connected by N-H?N hydrogen bonds with R 2 (2)(8) motifs, forming a supra-molecular ribbon along [101]. The crystal structure also features weak ?-? [centroid-centroid distances = 3.7638?(12) and 3.6008?(12)?Å] and C-H?? inter-actions.

SUBMITTER: Thanigaimani K 

PROVIDER: S-EPMC3685106 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature