Ontology highlight
ABSTRACT:
SUBMITTER: Wang HY
PROVIDER: S-EPMC3686126 | biostudies-literature | 2013 Apr
REPOSITORIES: biostudies-literature
Wang Hua-Yu Leo HY Guo Haibing H O'Doherty George A GA
Tetrahedron 20130401 16
An asymmetric synthesis of the di- and trisaccharide portion of the naturally occurring anthrax tetrasaccharide from acetylfuran has been developed. The construction of the di- and trisaccharide subunits is based upon our previously disclosed route to anthrax tetrasaccharide. The approach uses iterative diastereoselective palladium-catalyzed glycosylations, Luche reductions, diastereoselective dihydroxylations, and regioselective protections for the assembly of the rhamno- di- and tri-saccharide ...[more]