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Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.


ABSTRACT: Amine meets arene: A method for direct amination of ?-C(sp(2))-H bonds of benzoic acid derivatives and ?-C(sp(2))-H bonds of benzylamine derivatives has been developed. The reaction is catalyzed by Cu(OAc)2 and a Ag2CO3 cocatalyst, and shows high generality and functional-group tolerance, as well as providing a straightforward means for the preparation of ortho-aminobenzoic acid derivatives.

SUBMITTER: Tran LD 

PROVIDER: S-EPMC3734806 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.

Tran Ly Dieu LD   Roane James J   Daugulis Olafs O  

Angewandte Chemie (International ed. in English) 20130424 23


Amine meets arene: A method for direct amination of β-C(sp(2))-H bonds of benzoic acid derivatives and γ-C(sp(2))-H bonds of benzylamine derivatives has been developed. The reaction is catalyzed by Cu(OAc)2 and a Ag2CO3 cocatalyst, and shows high generality and functional-group tolerance, as well as providing a straightforward means for the preparation of ortho-aminobenzoic acid derivatives. ...[more]

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