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ABSTRACT:
SUBMITTER: Mtei RP
PROVIDER: S-EPMC3742805 | biostudies-literature | 2011 Dec
REPOSITORIES: biostudies-literature
Mtei Regina P RP Perera Eranda E Mogesa Benjamin B Stein Benjamin B Basu Partha P Kirk Martin L ML
European journal of inorganic chemistry 20111201 36
Metallo-dithiolene non-innocence is explored in an oxomolybdenum-bis(dithione) complex, [Mo<sup>4+</sup>O(<i>i</i>-Pr<sub>2</sub>Pipdt)<sub>2</sub>Cl][PF<sub>6</sub>] (where <i>i</i>-Pr<sub>2</sub>Pipdt is N,N'-piperazine-2,3-dithione), that possesses a piperazine ring as an integral part of the dithiolene ligand. The title complex displays unusual spectroscopic features for a formally reduced Mo(IV) dithiolene complex, namely a low energy metal-to-ligand charge transfer band with appreciable in ...[more]