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Bright Light Emission and Waveguiding in Conjugated Polymer Nanofibers Electrospun from Organic Salt Added Solutions.


ABSTRACT: Light-emitting electrospun nanofibers of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-( N,N '-diphenyl)- N,N '-di(p-butyl-oxy-phenyl)-1,4-diaminobenzene)] (PFO-PBAB) are produced by electrospinning under different experimental conditions. In particular, uniform fibers with average diameter of 180 nm are obtained by adding an organic salt to the electrospinning solution. The spectroscopic investigation assesses that the presence of the organic salt does not alter the optical properties of the active material, therefore providing an alternative approach for the fabrication of highly emissive conjugated polymer nanofibers. The produced nanofibers display self-waveguiding of light, and polarized photoluminescence, which is especially promising for embedding active electrospun fibers in sensing and nanophotonic devices.

SUBMITTER: Fasano V 

PROVIDER: S-EPMC3743350 | biostudies-literature | 2013 Aug

REPOSITORIES: biostudies-literature

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Bright Light Emission and Waveguiding in Conjugated Polymer Nanofibers Electrospun from Organic Salt Added Solutions.

Fasano Vito V   Polini Alessandro A   Morello Giovanni G   Moffa Maria M   Camposeo Andrea A   Pisignano Dario D  

Macromolecules 20130716 15


Light-emitting electrospun nanofibers of poly[(9,9-dioctylfluorenyl-2,7-diyl)-<i>co</i>-( <i><i>N,N</i></i> '-diphenyl)- <i><i>N,N</i></i> '-di(<i>p</i>-butyl-oxy-phenyl)-1,4-diaminobenzene)] (PFO-PBAB) are produced by electrospinning under different experimental conditions. In particular, uniform fibers with average diameter of 180 nm are obtained by adding an organic salt to the electrospinning solution. The spectroscopic investigation assesses that the presence of the organic salt does not al  ...[more]

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