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3-Ethyl-sulfinyl-2-(3-fluoro-phen-yl)-5-phenyl-1-benzo-furan.

ABSTRACT: In the title compound, C22H17FO2S, the dihedral angles between the mean plane [r.m.s. deviation = 0.005?(1)?Å] of the benzo-furan ring system and the pendant 3-fluoro-phenyl and phenyl rings are 23.92?(5) and 32.44?(5)°, respectively. In the crystal, mol-ecules are linked by two weak C-H?O(sulfin-yl) hydrogen bonds and a C-H?? inter-action, forming a sheet, which lies in the ab plane. A ?-? inter-action between the benzene and furan rings of neighbouring mol-ecules [centroid-centroid distance = 3.976?(2)?Å] links the mol-ecules into inversion dimers and connects adjacent sheets, resulting in a three-dimensional network.

SUBMITTER: Choi HD

PROVIDER: S-EPMC3770370 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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3-Ethyl-sulfinyl-2-(3-fluoro-phen-yl)-5-phenyl-1-benzo-furan.

Choi Hong Dae HD Seo Pil Ja PJ Lee Uk U

Acta crystallographica. Section E, Structure reports online 20130612 Pt 7

In the title compound, C22H17FO2S, the dihedral angles between the mean plane [r.m.s. deviation = 0.005 (1) Å] of the benzo-furan ring system and the pendant 3-fluoro-phenyl and phenyl rings are 23.92 (5) and 32.44 (5)°, respectively. In the crystal, mol-ecules are linked by two weak C-H⋯O(sulfin-yl) hydrogen bonds and a C-H⋯π inter-action, forming a sheet, which lies in the ab plane. A π-π inter-action between the benzene and furan rings of neighbouring mol-ecules [centroid-centroid distance = ...[more]

PMID: 24046655

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