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3-Acetyl-2,4-di-methyl-quinolin-1-ium chloride.

ABSTRACT: In the title salt, C13H14NO(+)·Cl(-), the dihedral angle between the fused ring system (r.m.s. deviation = 0.039?Å) and the attached aldehyde group is 75.27?(16)°. In the crystal, the cation and anion are linked by an N-H?Cl hydrogen bond and the resulting pairs are connected into four-ion aggregates by ?-? inter-actions between the C6 and pyridinium rings [3.6450?(9)?Å] of inversion-related quinolinium residues.

SUBMITTER: Prasath R

PROVIDER: S-EPMC3770407 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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3-Acetyl-2,4-di-methyl-quinolin-1-ium chloride.

Prasath R R Bhavana P P Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20130622 Pt 7

In the title salt, C13H14NO(+)·Cl(-), the dihedral angle between the fused ring system (r.m.s. deviation = 0.039 Å) and the attached aldehyde group is 75.27 (16)°. In the crystal, the cation and anion are linked by an N-H⋯Cl hydrogen bond and the resulting pairs are connected into four-ion aggregates by π-π inter-actions between the C6 and pyridinium rings [3.6450 (9) Å] of inversion-related quinolinium residues. ...[more]

PMID: 24046692

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