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8-Phenyl-16-thia-penta-cyclo-[6.6.5.0(1,18).0(2,7).0(9,14)]nona-deca-2,4,6,9,11,13,18-hepta-ene.

ABSTRACT: In the title compound, C24H18S, the dihedral angles between the phenyl ring and the two benzene rings of the anthracene moiety are 51.92?(9) and 68.24?(9)°, whereas the dihedral angle between the two anthracene benzene rings is 120.13?(9)°. The three non-aromatic six-membered rings are in boat conformations, while the five-membered ring has an envelope conformation on the S atom. In the crystal, there are three C-H?? inter-actions, which facilitate the packing of the mol-ecules.

SUBMITTER: Mathew EM

PROVIDER: S-EPMC3770424 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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8-Phenyl-16-thia-penta-cyclo-[6.6.5.0(1,18).0(2,7).0(9,14)]nona-deca-2,4,6,9,11,13,18-hepta-ene.

Mathew Eason M EM Sithambaresan M M Unnikrishnan P A PA Kurup M R Prathapachandra MR

Acta crystallographica. Section E, Structure reports online 20130629 Pt 7

In the title compound, C24H18S, the dihedral angles between the phenyl ring and the two benzene rings of the anthracene moiety are 51.92 (9) and 68.24 (9)°, whereas the dihedral angle between the two anthracene benzene rings is 120.13 (9)°. The three non-aromatic six-membered rings are in boat conformations, while the five-membered ring has an envelope conformation on the S atom. In the crystal, there are three C-H⋯π inter-actions, which facilitate the packing of the mol-ecules. ...[more]

PMID: 24046709

Similar Datasets

16-Oxa-penta-cyclo-[6.6.5.0(1,18).0(2,7).0(9,14)]nona-deca-2,4,6,9,11,13,18-heptaen-15-one.

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Methyl 11,14,16-triphenyl-8,12-dioxa-14,15-di-aza-tetra-cyclo-[8.7.0.0(2,7).0(13,17)]hepta-deca-2(7),3,5,13(17),15-penta-ene-10-carboxyl-ate.

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