Unknown

Dataset Information

0

4-Bromo-2-[5-methyl-2-(morpholin-4-yl)-1,3-thia-zol-4-yl]phenol.

ABSTRACT: In the title compound, C14H15BrN2O2S, synthesized by the reaction of the corresponding phenacyl thio-cyanate with morpholine, the dihedral angle between the 1,3-thia-zole ring and the phenolic substituent ring is 23.46?(10)° as a result of the steric influence of the ortho-methyl group on the thia-zole ring. A strong intra-molecular phenolic O-H?N hydrogen bond is present in the mol-ecule. In the crystal, a weak C-H?Ophenol hydrogen bond gives rise to chains lying parallel to [20-1]. A short inter-molecular Br?Omorpholine inter-action is also present [3.1338?(19)?Å].

SUBMITTER: Bahrin LG 

PROVIDER: S-EPMC3770429 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

4-Bromo-2-[5-methyl-2-(morpholin-4-yl)-1,3-thia-zol-4-yl]phenol.

Bahrin Lucian G LG   Hrib Cristian G CG   Birsa Lucian M LM  

Acta crystallographica. Section E, Structure reports online 20130629 Pt 7

In the title compound, C14H15BrN2O2S, synthesized by the reaction of the corresponding phenacyl thio-cyanate with morpholine, the dihedral angle between the 1,3-thia-zole ring and the phenolic substituent ring is 23.46 (10)° as a result of the steric influence of the ortho-methyl group on the thia-zole ring. A strong intra-molecular phenolic O-H⋯N hydrogen bond is present in the mol-ecule. In the crystal, a weak C-H⋯Ophenol hydrogen bond gives rise to chains lying parallel to [20-1]. A short int  ...[more]

Similar Datasets

Unknown 2-[(1,3-Benzothia-zol-2-yl)imino-meth-yl]-4-bromo-phenol.
| S-EPMC3089149 | biostudies-literature
Unknown 2-(6-Bromo-benzo[d]thia-zol-2-yl)-5,5-di-methyl-thia-zol-4(5H)-one.
| S-EPMC3885071 | biostudies-literature
Unknown 2-(2-Methyl-phen-yl)-N-(1,3-thia-zol-2-yl)acetamide.
| S-EPMC4051114 | biostudies-literature
Unknown 2-({[4-(1,3-Benzothia-zol-2-yl)phen-yl]amino}methyl)-phenol.
| S-EPMC3254391 | biostudies-literature
Unknown 5-Methyl-N-(1,3-thia-zol-2-yl)isoxazole-4-carboxamide.
| S-EPMC3684936 | biostudies-literature
Unknown N,N'-Bis(1,3-thia-zol-2-yl)methyl-ene-diamine.
| S-EPMC3238970 | biostudies-literature
Unknown 1-(5-Bromo-4-phenyl-1,3-thia-zol-2-yl)pyrrolidin-2-one.
| S-EPMC3379326 | biostudies-literature
Unknown {2-[(1,3-Benzo-thia-zol-2-yl)meth-oxy]-5-bromo-phen-yl}(phen-yl)methanone.
| S-EPMC3685117 | biostudies-literature
Unknown 3-(2-Amino-1,3-thia-zol-4-yl)-6-bromo-2H-chromen-2-one.
| S-EPMC2971769 | biostudies-literature
Unknown N-(1,3-Thia-zol-2-yl)benzamide.
| S-EPMC2969069 | biostudies-literature