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?-(Acetic acid)-di-?-chlorido-bis[tri-phenyl-tellurium(IV)] monohydrate.

ABSTRACT: The asymmetric unit of the title compound, C38H34Cl2O2Te2·H2O, contains two independent Te(IV) cations, each coordinated by three phenyl ligands, two Cl(-) anions and one acetic acid mol-ecule in a distorted octa-hedral C3Cl2O geometry; the longer Te?Cl distances ranging from 3.2007?(11) to 3.4407?(11)?Å and the longer Te?O distances of 3.067?(3) and 3.113?(3)?Å indicate the weak bridge coordination. The Cl(-) anion and acetic acid mol-ecule bridge the two independent Te(IV) cations, forming the dimeric complex mol-ecule, in which the Te?Te separation is 3.7314?(4)?Å. In the crystal, the water molecules of crystallization link the Te(IV) complex mol-ecules into chains running along the b-axis direction via O-H?O and O-H?Cl hydrogen bonds.

SUBMITTER: Hu F

PROVIDER: S-EPMC3770430 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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μ-(Acetic acid)-di-μ-chlorido-bis[tri-phenyl-tellurium(IV)] monohydrate.

Hu Feng F Xu Chao C Shi Hua-Tian HT Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20130629 Pt 7

The asymmetric unit of the title compound, C38H34Cl2O2Te2·H2O, contains two independent Te(IV) cations, each coordinated by three phenyl ligands, two Cl(-) anions and one acetic acid mol-ecule in a distorted octa-hedral C3Cl2O geometry; the longer Te⋯Cl distances ranging from 3.2007 (11) to 3.4407 (11) Å and the longer Te⋯O distances of 3.067 (3) and 3.113 (3) Å indicate the weak bridge coordination. The Cl(-) anion and acetic acid mol-ecule bridge the two independent Te(IV) cations, forming the ...[more]

PMID: 24046715

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