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Chlorido{1-[(dimethylamino)methyl]ferrocenyl-?(2) C (2),N}(tri-phenyl-stibine-?Sb)palladium(II).

ABSTRACT: In the title compound, [FePdCl(C5H5)(C8H11N)(C18H15Sb)], obtained by reaction of diphen-yl(N,N-di-methyl-amino-methyl-ferrocen-yl)stibine with sodium tetra-chlorido-palladate(II) in acetone, the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by a C atom of the ferrocenyl ring, and by N, Cl and Sb atoms. The Sb and N atoms are trans to each other.

SUBMITTER: Perez D

PROVIDER: S-EPMC3772412 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Chlorido{1-[(dimethylamino)methyl]ferrocenyl-κ(2) C (2),N}(tri-phenyl-stibine-κSb)palladium(II).

Pérez Diego D Sharma Pankaj P Sharma Manju M Hernández Simón S

Acta crystallographica. Section E, Structure reports online 20130608 Pt 7

In the title compound, [FePdCl(C5H5)(C8H11N)(C18H15Sb)], obtained by reaction of diphen-yl(N,N-di-methyl-amino-methyl-ferrocen-yl)stibine with sodium tetra-chlorido-palladate(II) in acetone, the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by a C atom of the ferrocenyl ring, and by N, Cl and Sb atoms. The Sb and N atoms are trans to each other. ...[more]

PMID: 24046555

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