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Ultrafast zero balance of the oscillator-strength sum rule in graphene.


ABSTRACT: Oscillator-strength sum rule in light-induced transitions is one general form of quantum-mechanical identities. Although this sum rule is well established in equilibrium photo-physics, an experimental corroboration for the validation of the sum rule in a nonequilibrium regime has been a long-standing unexplored question. The simple band structure of graphene is an ideal system for investigating this question due to the linear Dirac-like energy dispersion. Here, we employed both ultrafast terahertz and optical spectroscopy to directly monitor the transient oscillator-strength balancing between quasi-free low-energy oscillators and high-energy Fermi-edge ones. Upon photo-excitation of hot Dirac fermions, we observed that the ultrafast depletion of high-energy oscillators precisely complements the increased terahertz absorption oscillators. Our results may provide an experimental priori to understand, for example, the intrinsic free-carrier dynamics to the high-energy photo-excitation, responsible for optoelectronic operation such as graphene-based phototransistor or solar-energy harvesting devices.

SUBMITTER: Kim J 

PROVIDER: S-EPMC3773626 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Ultrafast zero balance of the oscillator-strength sum rule in graphene.

Kim Jaeseok J   Lim Seong Chu SC   Chae Seung Jin SJ   Maeng Inhee I   Choi Younghwan Y   Cha Soonyoung S   Lee Young Hee YH   Choi Hyunyong H  

Scientific reports 20130101


Oscillator-strength sum rule in light-induced transitions is one general form of quantum-mechanical identities. Although this sum rule is well established in equilibrium photo-physics, an experimental corroboration for the validation of the sum rule in a nonequilibrium regime has been a long-standing unexplored question. The simple band structure of graphene is an ideal system for investigating this question due to the linear Dirac-like energy dispersion. Here, we employed both ultrafast teraher  ...[more]

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