Ontology highlight
ABSTRACT:
SUBMITTER: Hirose D
PROVIDER: S-EPMC3778400 | biostudies-literature | 2013
REPOSITORIES: biostudies-literature
Hirose Daisuke D Taniguchi Tsuyoshi T
Beilstein journal of organic chemistry 20130820
Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C-H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previously, gives nitrated γ-lactols, whereas the reaction in the presence of water produces 4-hydroxy-5-nitropentyl nitrate or 4-hydroxy-3-nitropentyl nitrate derivatives. ...[more]