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Poly[tetra-methyl-ammonium [tri-?2-formato-?(6) O:O'-manganate(II)]].

ABSTRACT: In the title compound, {(C4H12N)[Mn(HCO2)3]} n , the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetra-methyl-ammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C-H?O hydrogen bonds with the formate ligands.

SUBMITTER: Han CY

PROVIDER: S-EPMC3790351 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Poly[tetra-methyl-ammonium [tri-μ2-formato-κ(6) O:O'-manganate(II)]].

Han Cai-Yun CY Liu Min-Min MM Dang Qin-Qin QQ

Acta crystallographica. Section E, Structure reports online 20130912 Pt 10

In the title compound, {(C4H12N)[Mn(HCO2)3]} n , the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetra-methyl-ammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C-H⋯O hydrogen bo ...[more]

PMID: 24098173

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