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Bis[2-(1,3-benzo-thia-zol-2-yl)phenyl-?(2) C (1),N][1,3-bis-(4-bromo-phen-yl)propane-1,3-dionato-?(2) O,O']iridium(III).

ABSTRACT: The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis-(bromo-phen-yl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octa-hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia-zole ring systems in the complex is 77.45?(10)°.

SUBMITTER: Kim YI

PROVIDER: S-EPMC3793684 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Bis[2-(1,3-benzo-thia-zol-2-yl)phenyl-κ(2) C (1),N][1,3-bis-(4-bromo-phen-yl)propane-1,3-dionato-κ(2) O,O']iridium(III).

Kim Young-Inn YI Yun Seong-Jae SJ Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20130710 Pt 8

The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis-(bromo-phen-yl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octa-hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia-zole ring systems in the complex is 77.45 (10)°. ...[more]

PMID: 24109271

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