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N-(3-Meth-oxy-benzo-yl)-2-methyl-benzene-sulfonamide.


ABSTRACT: In the title compound, C15H15NO4S, the dihedral angle between the methyl- and meth-oxy-substituted benzene rings is 88.99?(12)°. An intra-molecular C-H?O hydrogen bond occurs. In the crystal, adjacent mol-ecules form inversion-related dimers through strong N-H?O hydrogen bonds, generating R 2 (2)(8) loops. The dimers are further connected through C-H?O inter-actions that form C(8) chains parallel to (001). Mol-ecules are also connected through other C-H?O hydrogen bonds along the b axis, forming additional C(8) chains. Two aromatic ?-? stacking inter-actions [centroid-centroid separations = 3.6150?(1) and 3.6837?(1)?Å] generate a three-dimensional architecture.

SUBMITTER: Sreenivasa S 

PROVIDER: S-EPMC3793736 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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N-(3-Meth-oxy-benzo-yl)-2-methyl-benzene-sulfonamide.

Sreenivasa S S   Darshan D D   Prakash Shet M M   Mohan N R NR   Kumar Vijith V   Suchetan P A PA  

Acta crystallographica. Section E, Structure reports online 20130710 Pt 8


In the title compound, C15H15NO4S, the dihedral angle between the methyl- and meth-oxy-substituted benzene rings is 88.99 (12)°. An intra-molecular C-H⋯O hydrogen bond occurs. In the crystal, adjacent mol-ecules form inversion-related dimers through strong N-H⋯O hydrogen bonds, generating R 2 (2)(8) loops. The dimers are further connected through C-H⋯O inter-actions that form C(8) chains parallel to (001). Mol-ecules are also connected through other C-H⋯O hydrogen bonds along the b axis, forming  ...[more]

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