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Spontaneous chiral resolution directed by symmetry restriction and ?-? interaction.

ABSTRACT: In order to understand and rationally construct homochiral self-assembled structures from racemic molecules, two novel crystalline metal-organic frameworks with chiral cavities were developed. The homochirality of the layers in both MOFs was achieved by forming strong coordinate bonds between the C3-symmetric cyclotriveratrylene and Zn4O(CO2)6 cluster. By changing weak ?-? interactions between organic building blocks, the achiral assembly of ZnCTV-1 was successfully transformed into a chiral assembly in ZnCTV-2. This study demonstrated a possible route for designing the synthesis of chiral MOF through weak interactions.

SUBMITTER: Yu JT

PROVIDER: S-EPMC3796745 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Spontaneous chiral resolution directed by symmetry restriction and π-π interaction.

Yu Jin-Tao JT Shi Yan-Yan YY Sun Junliang J Lin Jianhua J Huang Zhi-Tang ZT Zheng Qi-Yu QY

Scientific reports 20131015

In order to understand and rationally construct homochiral self-assembled structures from racemic molecules, two novel crystalline metal-organic frameworks with chiral cavities were developed. The homochirality of the layers in both MOFs was achieved by forming strong coordinate bonds between the C3-symmetric cyclotriveratrylene and Zn4O(CO2)6 cluster. By changing weak π-π interactions between organic building blocks, the achiral assembly of ZnCTV-1 was successfully transformed into a chiral ass ...[more]

PMID: 24126555

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