Unknown

Dataset Information

0

Base-Induced Instability of Fluorotelomer Alcohols.

ABSTRACT: The stability of fluorotelomer alcohols under basic conditions was studied. HF elimination across the CF2-CH2 junction is shown to be facilitated by an intramolecular hydrogen bond, while solvation is the key determinant in the stability of alcohols of various perfluoroalkyl lengths. Finally, fluorotelomer alcohols can be rendered kinetically stable if either the alcohol or the base has low solubility in the reaction medium.

SUBMITTER: Tucker WB 

PROVIDER: S-EPMC3834964 | biostudies-literature | 2013 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Base-Induced Instability of Fluorotelomer Alcohols.

Tucker William B WB   Mecozzi Sandro S  

Journal of fluorine chemistry 20131201

The stability of fluorotelomer alcohols under basic conditions was studied. HF elimination across the CF<sub>2</sub>-CH<sub>2</sub> junction is shown to be facilitated by an intramolecular hydrogen bond, while solvation is the key determinant in the stability of alcohols of various perfluoroalkyl lengths. Finally, fluorotelomer alcohols can be rendered kinetically stable if either the alcohol or the base has low solubility in the reaction medium. ...[more]

Similar Datasets

Unknown Estrogen-like properties of fluorotelomer alcohols as revealed by mcf-7 breast cancer cell proliferation.
| S-EPMC1332663 | biostudies-literature
Unknown Gas-Phase Detection of Fluorotelomer Alcohols and Other Oxygenated Per- and Polyfluoroalkyl Substances by Chemical Ionization Mass Spectrometry.
| S-EPMC6550326 | biostudies-literature
Unknown Triphosgene-amine base promoted chlorination of unactivated aliphatic alcohols.
| S-EPMC4153350 | biostudies-literature
Unknown Base Metal-Catalyzed Direct Olefinations of Alcohols with Sulfones.
| S-EPMC6648817 | biostudies-literature
Unknown Base-Promoted C-C Bond Activation Enables Radical Allylation with Homoallylic Alcohols.
| S-EPMC7021447 | biostudies-literature
Unknown p53 coordinates base excision repair to prevent genomic instability.
| S-EPMC4838360 | biostudies-literature
Unknown Biotransformation of AFFF Component 6:2 Fluorotelomer Thioether Amido Sulfonate Generates 6:2 Fluorotelomer Thioether Carboxylate under Sulfate-Reducing Conditions.
| S-EPMC6350918 | biostudies-literature
Unknown Cytosine deamination and base excision repair cause R-loop-induced CAG repeat fragility and instability in <i>Saccharomyces cerevisiae</i>.
| S-EPMC5635916 | biostudies-literature
Unknown Influence of Asian and Western United States urban areas and fires on the atmospheric transport of polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and fluorotelomer alcohols in the Western United States.
| S-EPMC4145841 | biostudies-literature
Genomics Cyclophosphomide-induced genome instability
2019-09-18 | PRJEB34208 | EVA