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Direct formation of tethered Ru(II) catalysts using arene exchange.

ABSTRACT: An 'arene exchange' approach has been successfully applied for the first time to the synthesis of Ru(II)-based 'tethered' reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones.

SUBMITTER: Soni R 

PROVIDER: S-EPMC3856772 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Direct formation of tethered Ru(II) catalysts using arene exchange.

Soni Rina R   Jolley Katherine E KE   Clarkson Guy J GJ   Wills Martin M  

Organic letters 20130926 19

An 'arene exchange' approach has been successfully applied for the first time to the synthesis of Ru(II)-based 'tethered' reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones. ...[more]

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