Water Adsorption at the Tetrahedral Titania Surface Layer of SrTiO₃(110)-(4 × 1).

ABSTRACT: The interaction of water with oxide surfaces is of great interest for both fundamental science and applications. We present a combined theoretical (density functional theory (DFT)) and experimental (scanning tunneling microscopy (STM) and photoemission spectroscopy (PES)) study of water interaction with the two-dimensional titania overlayer that terminates the SrTiO₃(110)-(4 × 1) surface and consists of TiO₄ tetrahedra. STM and core-level and valence band PES show that H₂O neither adsorbs nor dissociates on the stoichiometric surface at room temperature, whereas it does dissociate at oxygen vacancies. This is in agreement with DFT calculations, which show that the energy barriers for water dissociation on the stoichiometric and reduced surfaces are 1.7 and 0.9 eV, respectively. We propose that water weakly adsorbs on two-dimensional, tetrahedrally coordinated overlayers.

SUBMITTER: Wang Z 

PROVIDER: S-EPMC3864247 | biostudies-literature | 2013 Dec

REPOSITORIES: biostudies-literature