Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Cloud point extraction of parabens using non-ionic surfactant with cylodextrin functionalized ionic liquid as a modifier.

ABSTRACT: A cloud point extraction (CPE) process using non-ionic surfactant (DC193C) to extract selected paraben compounds from water samples was investigated using reversed phase high performance liquid chromatography (RP-HPLC). The CPE process with the presence of ?-cyclodextrin (?CD) functionalized ionic liquid as a modifier (CPE-DC193C-?CD-IL) is a new extraction technique that has been applied on the optimization of parameters, i.e., pH, ?CD-IL concentration and phase volume ratio. This CPE-DC193C-?CD-IL method is facilitated at 30 °C, showing great losses of water content in the surfactant-rich phase, resulting in a high pre-concentration factor and high distribution coefficient. The developed method CPE-DC193C-?CD-IL did show enhanced properties compared to the CPE method without the modifier (CPE-DC193C). The developed method of CPE-DC193C-?CD-IL gives an excellent performance on the detection of parabens from water samples with the limit of detection falling in the range of 0.013-0.038 µg mL-1. Finally, the inclusion complex formation, hydrogen bonding, and ?-? interaction between the ?CD-IL, benzyl paraben (ArP), and DC 193C were proven using 1H NMR and 2D NOESY spectroscopy.

SUBMITTER: Noorashikin MS

PROVIDER: S-EPMC3876126 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Cloud point extraction of chlorophylls from spinach leaves using aqueous solutions of non-ionic surfactants.

Project description:Chlorophylls and their derivatives are currently used in a wide range of applications. To replace the volatile organic solvents commonly applied for their extraction from biomass, aqueous solutions of non-ionic surfactants are studied herein in the extraction of chlorophylls from spinach leaves. Aqueous solutions of several surfactants were screened, demonstrating that their hydrophilic-lipophilic balance (HLB) plays the pivotal role on the extraction performance, with the best results obtained for surfactants with a HLB ranging between 10 and 13. A response surface methodology (RSM) was then used to optimize operational conditions (surfactant concentration, solid-liquid ratio and temperature), leading to a maximum extraction yield of chlorophylls of 0.94 mg/g. After the extraction step, the chlorophylls-rich extract was concentrated by heating above the surfactant-water cloud point, leading to the separation into two-phases, and to a concentration factor of 9 and a recovery of 97% of chlorophylls in the surfactant-rich phase. The antioxidant activity of the extracts was finally appraised, showing that the antioxidant activity of the aqueous chlorophylls-rich extracts is higher than that obtained with volatile organic solvents. The obtained results show the potential of aqueous solutions of non-ionic surfactants to extract highly hydrophobic compounds from biomass and their possible direct use in cosmetic and nutraceutical applications, without requiring an additional recovery or purification step.

| S-EPMC6161820 | biostudies-literature

Surface-Active Ionic Liquid-Assisted Cloud Point Extraction for Pre-Concentration and Determination of Cobalt Ions in Pharmaceutical Preparations.

Project description:Herein we describe an efficient, simple, and precise micelle-mediated microextraction strategy based on the aggregation behavior of surface-active ionic liquids (SAILs) for the preconcentration and determination of cobalt ions in pharmaceutical preparations. Unlike the commonly used hydrophobic ionic liquids in IL-based microextraction methods, a water-soluble surface-active ionic liquid [1-hexadecyl 3-methylimidazolium chloride (C16MeImCl)] was used. A modified cloud point extraction (CPE) procedure based on the C16MeImCl-Triton X-114 mixed micellar system was proposed as an efficient extracting phase. A comparison of the analytical features of the extraction process with and without SAILs revealed the benefits of the proposed method. Advantages such as a wider linear range, lower detection limit, higher reproducibility, and improved extraction efficiency highlighted the proposed method over the conventional CPE method. These attractive specifications are due to the higher extraction efficiencies achieved in the presence of the SAIL and its favorable effects at the phase separation stage. Various parameters affecting the extraction efficiency were optimized by univariate and multivariate (Box-Behnken design) approaches. The calibration curve was obtained in the optimal experimental conditions with a linear range from 0.01 to 5.5 mg L-1 of cobalt ion concentration (R = 0.9992) and a detection limit of about 0.005 mg L-1. The RSD% for 10 replicate determinations of 1.0 mg L-1 Co was 0.9%. The proposed method was successfully applied to determine cobalt ions in vitamin B12 ampoules and tablets.

| S-EPMC9347226 | biostudies-literature

Formulation of chelating agent with surfactant in cloud point extraction of methylphenol in water.

Project description:Cloud point extraction (CPE) is a separation and preconcentration of non-ionic surfactant from one liquid phase to another. In this study, Sylgard 309 and three different types of additives for CPE, namely CPE-Sylgard, CPE-Sylgard-BMIMBr and CPE-Sylgard-GLDA, are investigated to extract methylphenol from water samples. The methylphenols are well separated by reversed-phase high-performance liquid chromatography (HPLC) with isocratic elution of acetonitrile : water; 60 : 40 (v/v) and detection at 260 nm. The optimized parameters for the effect of salt, surfactant, temperature, time of extraction, pH, interference study and the performance of different additives on methylphenol extraction are investigated. CPE-Sylgard-GLDA is chosen because it gives us a high peak and good peak area compared with CPE-Sylgard and CPE-Sylgard-BMIMBr. The recovery extractions of CPE-Sylgard-GLDA are obtained in the range of 80-99% as the percentage of relative standard deviation (RSD) is less than 10. The LOD and LOQ are 0.05 ppm and 0.18 ppm, respectively. The method developed for CPE-Sylgard-GLDA coupled with HPLC is feasible for the determination of methylphenol because it is simple, effective, cheap, and produces a high percentage of recovery.

| S-EPMC6083667 | biostudies-literature

Cloud Point Extraction for Electroanalysis: Anodic Stripping Voltammetry of Cadmium.

Project description:Cloud point extraction (CPE) is a well-established technique for the preconcentration of hydrophobic species from water without the use of organic solvents. Subsequent analysis is then typically performed via atomic absorption spectroscopy (AAS), UV-vis spectroscopy, or high performance liquid chromatography (HPLC). However, the suitability of CPE for electroanalytical methods such as stripping voltammetry has not been reported. We demonstrate the use of CPE for electroanalysis using the determination of cadmium (Cd(2+)) by anodic stripping voltammetry (ASV). Rather than using the chelating agents which are commonly used in CPE to form a hydrophobic, extractable metal complex, we used iodide and sulfuric acid to neutralize the charge on Cd(2+) to form an extractable ion pair. This offers good selectivity for Cd(2+) as no interferences were observed from other heavy metal ions. Triton X-114 was chosen as the surfactant for the extraction because its cloud point temperature is near room temperature (22-25 °C). Bare glassy carbon (GC), bismuth-coated glassy carbon (Bi-GC), and mercury-coated glassy carbon (Hg-GC) electrodes were compared for the CPE-ASV. A detection limit for Cd(2+) of 1.7 nM (0.2 ppb) was obtained with the Hg-GC electrode. ASV with CPE gave a 20x decrease (4.0 ppb) in the detection limit compared to ASV without CPE. The suitability of this procedure for the analysis of tap and river water samples was demonstrated. This simple, versatile, environmentally friendly, and cost-effective extraction method is potentially applicable to a wide variety of transition metals and organic compounds that are amenable to detection by electroanalytical methods.

| S-EPMC4889431 | biostudies-literature

Application of a functionalized ionic liquid extractant tributylmethylammonium dibutyldiglycolamate ([A336][BDGA]) in light rare earth extraction and separation.

Project description:A type of functionalized ionic liquid extractant, tributylmethylammonium dibutyldiglycolamate ([A336][BDGA]), was synthesized, and its extraction ability of light rare earth elements, namely, La(III), Ce(III), Pr(III) and Nd(III), wascompared with that of other functionalized ionic liquid extractants, including tributylmethylammonium dioctyldiglycolamate and diglycolic amide extractants N,N,N,N-tetrabutyl-3-oxapentane-diamide (TBDGA) and N,N,N,N-tetraoctyl-3-oxapentane-diamide (TODGA). The study of extraction behavior indicated that the ionic liquids exhibited better extraction properties than the amides under lower acidity conditions. The effects of the pH and concentration of the extractant on the extraction behavior of [A336][BDGA] on light rare earths were determined. A separation strategy of mixed light rare earths was investigated by means of extraction chromatography using [A336][BDGA] as the stationary phase. As a result, nearly pure La(III), Ce(III), Pr(III) and Nd(III) were obtained, respectively. A new strategy of separating mixed light rare earths was established by means of extraction chromatography. The stationary phase of [A336][BDGA] was used in this strategy. The four rare earths elements, La(III), Ce(III), Pr(III) and Nd(III), achieved baseline separation.

| S-EPMC6107113 | biostudies-literature

Performance evaluation of non-ionic silicone surfactants OFX 0309 and DC 193C as a new approach in cloud point extraction - spectrophotometry for determination of atrazine in water samples.

Project description:Cloud point extraction (CPE) - spectrophotometric method had been adopted for the separation of atrazine using the non-ionic silicone surfactant, polysiloxane polyether, as a new approach of atrazine extractor in CPE. There were two types of polysiloxane polyether (DC 193C and OFX 0309) studied to investigate the effectiveness of these surfactants toward atrazine in CPE method. Various effects of operating parameters such as the concentration of surfactant and atrazine, addition of salt and change of temperature and pH on the extraction of atrazine have been studied in detail to find the optimum conditions. The limit of detections (LODs) and quantifications (LOQs) were in the range of 0.09-0.59 μg L-1 and 0.31-1.95 μg L-1 in water samples, respectively. The method recoveries at two spiked levels were 84-105% (CPE-OFX 0309) and 59-69% (CPE-DC 193C) with good correlation of determination (R 2) ranging from 0.9927-0.9993 for both methods. The Langmuir isotherm has been used for solubilisation study of surfactant and atrazine. The thermodynamic parameters have been determined such as Gibbs free energy (ΔG°) which increases with temperature, value of enthalpy (ΔH°) and value of entropy (ΔS°) which increase with the surfactant hydrophobicity.

| S-EPMC9079888 | biostudies-literature

Conductive Hybrid Crystal Composed from Polyoxomolybdate and Deprotonatable Ionic-Liquid Surfactant.

Project description:A polyoxomolybdate inorganic-organic hybrid crystal was synthesized with deprotonatable ionic-liquid surfactant. 1-dodecylimidazolium cation was employed for its synthesis. The hybrid crystal contained δ-type octamolybdate (Mo₈) isomer, and possessed alternate stacking of Mo₈ monolayers and interdigitated surfactant bilayers. The crystal structure was compared with polyoxomolybdate hybrid crystals comprising 1-dodecyl-3-methylimidazolium surfactant, which preferred β-type Mo₈ isomer. The less bulky hydrophilic moiety of the 1-dodecylimidazolium interacted with the δ-Mo₈ anion by N-H···O hydrogen bonds, which presumably induced the formation of the δ-Mo₈ anion. Anhydrous conductivity of the hybrid crystal was estimated to be 5.5 × 10(-6) S·cm(-1) at 443 K by alternating current (AC) impedance spectroscopy.

| S-EPMC4964370 | biostudies-literature

Triphilic Ionic-Liquid Mixtures: Fluorinated and Non-fluorinated Aprotic Ionic-Liquid Mixtures.

Project description:We present here the possibility of forming triphilic mixtures from alkyl- and fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which instead of the often observed two domains-polar and nonpolar-three stable microphases are present: polar, lipophilic, and fluorous ones. The fluorinated side chains of the cations indeed self-associate and form domains that are segregated from those of the polar and alkyl domains. To enable miscibility, despite the generally preferred macroscopic separation between fluorous and alkyl moieties, the importance of strong hydrogen bonding is shown. As the long-range structure in the alkyl and fluoroalkyl domains is dependent on the composition of the liquid, we propose that the heterogeneous, triphilic structure can be easily tuned by the molar ratio of the components. We believe that further development may allow the design of switchable, smart liquids that change their properties in a predictable way according to their composition or even their environment.

| S-EPMC4641458 | biostudies-literature

Ionic liquid-supported magnetite nanoparticles as electrode modifier materials for estrogens sensing.

Project description:This paper reports the application of a carbon paste electrode modified with magnetite nanoparticles and the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate in the electroanalytical determination of 17?-estradiol and estriol. These estrogens are potential endocrine disruptors and thus it is relevant the development of devices for their monitoring. Transmission electron microscopy, scanning electron microscopy and zeta potential techniques were applied to characterization of the modifier materials. In cyclic voltammetry experiments, irreversible oxidation peaks were observed for 17?-estradiol and estriol at +0.320?V and +0.400?V, respectively. The anodic currents obtained were approximately three times greater than those provided by the unmodified electrode due to the presence of magnetic nanoparticles and the ionic liquid, which improved the sensitivity of modified electrode. For the analysis, the parameters of the square-wave voltammetry (scan increment, amplitude and frequency) were optimized by Box-Behnken factorial design for each estrogen. For 17?-estradiol in B-R buffer pH 12.0, the calibration plot was linear from 0.10 to 1.0??mol L-1, with a detection limit of 50.0 nmol L-1. For estriol in B-R buffer pH 11.0, the linear range was 1.0 to 10.0??mol L-1, with a detection limit of 300.0 nmol L-1. The modified electrode was applied in the determination of 17?-estradiol and estriol in pharmaceutical formulations and the results were comparable to those obtained using UV/VIS spectrometry. Statistical tests were applied to evaluate the results and it was concluded that there was no significant difference regarding the precision and accuracy of the data provided by the two methods.

| S-EPMC7005039 | biostudies-literature

Method for extraction of airborne LiDAR point cloud buildings based on segmentation.

Project description:The LiDAR technology is a means of urban 3D modeling in recent years, and the extraction of buildings is a key step in urban 3D modeling. In view of the complexity of most airborne LiDAR building point cloud extraction algorithms that need to combine multiple feature parameters, this study proposes a building point cloud extraction method based on the combination of the Point Cloud Library (PCL) region growth segmentation and the histogram. The filtered LiDAR point cloud is segmented by using the PCL region growth method, and then the local normal vector and direction cosine are calculated for each cluster after segmentation. Finally, the histogram is generated to effectively separate the building point cloud from the non-building.Two sets of airborne LiDAR data in the south and west parts of Tokushima, Japan, are used to test the feasibility of the proposed method. The results are compared with those of the commercial software TerraSolid and the K-means algorithm. Results show that the proposed extraction algorithm has lower type I and II errors and better extraction effect than that of the TerraSolid and the K-means algorithm.

| S-EPMC7259685 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data