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Tert-Butyl N-(thio-phen-2-yl)carbamate.

ABSTRACT: In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79?(14)°. In the crystal structure, intra-molecular C-H?O inter-actions in tandem with the tert-butyl groups render the packing of adjacent mol-ecules in the [001] direction nearly perpendicular [the angle between adjacent thio-phene rings is 74.83?(7)°]. An inter-molecular N-H?O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

SUBMITTER: Hsu GC

PROVIDER: S-EPMC3884429 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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tert-Butyl N-(thio-phen-2-yl)carbamate.

Hsu Gene C GC Singer Laci M LM Cordes David B DB Findlater Michael M

Acta crystallographica. Section E, Structure reports online 20130814 Pt 9

In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intra-molecular C-H⋯O inter-actions in tandem with the tert-butyl groups render the packing of adjacent mol-ecules in the [001] direction nearly perpendicular [the angle between adjacent thio-phene rings is 74.83 (7)°]. An inter-molecular N-H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin ...[more]

PMID: 24427049

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