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6-Ferrocenoyl-7-(4-fluoro-phen-yl)spiro-[hexa-hydro-pyrrolo-[1,2-c][1,3]thia-zole-5,11'-indeno-[1,2-b]quinoxaline].


ABSTRACT: In the title compound, [Fe(C5H5)(C32H23FN3OS)], both the thia-zolidine ring and the pyrrolidine ring adopt a twist conformation on the N-C(H) bridging bond. Their mean planes are inclined to one another by 10.05?(10)°, and they make dihedral angles of 82.09?(10) and 89.67?(11)°, respectively, with the cyclo-pentane ring. The F atom deviates by -0.0238?(2)?Å from the benzene ring to which it is attached. In the crystal, mol-ecules are linked by a pair of C-H?O hydrogen bonds, forming inversion dimers.

SUBMITTER: Suhitha S 

PROVIDER: S-EPMC3884446 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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6-Ferrocenoyl-7-(4-fluoro-phen-yl)spiro-[hexa-hydro-pyrrolo-[1,2-c][1,3]thia-zole-5,11'-indeno-[1,2-b]quinoxaline].

Suhitha Sivasubramanian S   Gunasekaran Krishnaswamy K   Gavaskar Deivasigamani D   Raghunathan Raghavachary R   Velmurugan Devadasan D  

Acta crystallographica. Section E, Structure reports online 20130817 Pt 9


In the title compound, [Fe(C5H5)(C32H23FN3OS)], both the thia-zolidine ring and the pyrrolidine ring adopt a twist conformation on the N-C(H) bridging bond. Their mean planes are inclined to one another by 10.05 (10)°, and they make dihedral angles of 82.09 (10) and 89.67 (11)°, respectively, with the cyclo-pentane ring. The F atom deviates by -0.0238 (2) Å from the benzene ring to which it is attached. In the crystal, mol-ecules are linked by a pair of C-H⋯O hydrogen bonds, forming inversion di  ...[more]

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