Unknown

Dataset Information

0

Poly[[bis-[?2-1,2-bis-(pyridin-4-yl)ethene-?(2) N:N']bis-(thio-cyanato-?N)cobalt(II)] 1,2-bis-(pyridin-4-yl)ethene monosolvate dihydrate].

ABSTRACT: The asymmetric unit of the title compound, {[Co(NCS)2(C12H10N2)2]·C12H10N2·2H2O} n , consists of two independent Co(II) cations, four distinct thio-cyanate anions, six 1,2-bis-(pyridin-4-yl)ethene (4-bpe) mol-ecules and four lattice water mol-ecules. The Co(II) cations are each coordinated by two N-bonded thio-cyanate anions and four 4-bpe ligands within a slightly distorted CoN6 octa-hedron. The two independent Co(II) cations are linked by the 4-bpe ligands into two distinct layers, parallel to the ac and bc planes, that inter-penetrate. From this arrangement, channels are formed in which non-coordinated 4-bpe and lattice water mol-ecules are hydrogen-bonded into chains that elongate in the c-axis direction.

SUBMITTER: Wohlert S 

PROVIDER: S-EPMC3884497 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Poly[[bis-[μ2-1,2-bis-(pyridin-4-yl)ethene-κ(2) N:N']bis-(thio-cyanato-κN)cobalt(II)] 1,2-bis-(pyridin-4-yl)ethene monosolvate dihydrate].

Wöhlert Susanne S   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20130810 Pt 9

The asymmetric unit of the title compound, {[Co(NCS)2(C12H10N2)2]·C12H10N2·2H2O} n , consists of two independent Co(II) cations, four distinct thio-cyanate anions, six 1,2-bis-(pyridin-4-yl)ethene (4-bpe) mol-ecules and four lattice water mol-ecules. The Co(II) cations are each coordinated by two N-bonded thio-cyanate anions and four 4-bpe ligands within a slightly distorted CoN6 octa-hedron. The two independent Co(II) cations are linked by the 4-bpe ligands into two distinct layers, parallel to  ...[more]

Similar Datasets

Unknown A triclinic polymorph of poly[[bis-[?-1,2-bis-(pyridin-4-yl)ethene-?(2)N:N']bis-(thio-cyanato-?N)cobalt(II)] 1,2-bis-(pyridin-4-yl)ethene monosolvate].
| S-EPMC3379076 | biostudies-literature
Unknown Diaqua-bis-[1,2-bis-(pyridin-4-yl)ethene]-bis-[2-(4-carboxy-phen-yl)acetato]-cobalt(II).
| S-EPMC3152052 | biostudies-literature
Unknown Diaqua-bis-[N-(pyridin-4-yl)isonicotin-amide-?N]bis-(thio-cyanato-?N)cobalt(II).
| S-EPMC3393148 | biostudies-literature
Unknown Crystal structure of catena-poly[[[di-aqua-[1,2-bis(pyridin-4-yl)ethene]{4-[2-(pyridin-4-yl)ethen-yl]pyridinium}gold(I)iron(II)]-di-?-cyanido] bis-[dicyanido-gold(I)] 1,2-bis-(pyridin-4-yl)ethene dihydrate].
| S-EPMC7274000 | biostudies-literature
Unknown catena-Poly[[[bis-(methanol-?O)bis-(seleno-cyanato-?N)manganese(II)]-?-1,2-bis-(pyridin-4-yl)ethane-?(2) N:N'] 1,2-bis-(pyridin-4-yl)ethane monosolvate].
| S-EPMC3629498 | biostudies-literature
Unknown catena-Poly[(E)-4,4'-(ethene-1,2-di-yl)dipyridinium [[bis-(thio-cyanato-?N)ferrate(II)]-di-?-thio-cyanato-?N:S;?S:N]].
| S-EPMC2983361 | biostudies-literature
Unknown Bis[tetra-kis-(pyridin-2-yl)methane-?(3) N,N',N'']cobalt(II) tetra-kis-(thio-cyanato-?N)cobaltate(II) methanol monosolvate.
| S-EPMC3998407 | biostudies-literature
Unknown Bis{N(2),N(6)-bis-[(pyridin-3-yl)meth-yl]pyridine-2,6-dicarboxamide-?N}bis-(methanol-?O)bis-(thio-cyanato-?N)cobalt(II).
| S-EPMC3379100 | biostudies-literature
Unknown cis-Tri-aqua-[1,1'-(propane-1,3-di-yl)bis-(pyridin-1-ium-4-carboxyl-ato)-?O]bis-(thio-cyanato-?N)manganese(II) dihydrate.
| S-EPMC3998253 | biostudies-literature
Unknown Di-?-thio-cyanato-bis-{[1,2-bis-(diiso-propyl-phosphan-yl)-1,2-dicarba-closo-dodeca-borane]silver(I)}.
| S-EPMC3050408 | biostudies-literature