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Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta-cyanido-nitro-soferrate(II).

ABSTRACT: The asymmetric unit of the title complex [Cu(C14H12N2)2]2[Fe(CN)5(NO)], consists of a [Cu(dmp)2](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)5(NO)](2-) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å) from the inversion center in the direction of the disordered trans-coordinating CN/NO ligands. The anion has a distorted octa-hedral coordination geometry. The Cu(I) ion is coordinated by two phenanthroline ligands in a distorted tetra-hedral geometry. The dihedral angle between the phenanthroline ligands is 77.16?(4)?Å. In the crystal, the cations are connected to the anions by weak C-H?N hydrogen bonds. In addition, weak ?-? stacking inter-actions are observed, with centroid-centroid distances in the range 3.512?(3)-3.859?(3)?Å.

SUBMITTER: Rusanova JA

PROVIDER: S-EPMC3885010 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta-cyanido-nitro-soferrate(II).

Rusanova Julia A JA Kozachuk Olesia V OV Semenaka Valentyna V VV Dyakonenko Viktoriya V VV

Acta crystallographica. Section E, Structure reports online 20131127 Pt 12

The asymmetric unit of the title complex [Cu(C14H12N2)2]2[Fe(CN)5(NO)], consists of a [Cu(dmp)2](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)5(NO)](2-) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å) from the inversion center in the direction of the disordered trans-coordinating CN/NO ligands. The anion has a distorted octa-hedral coordination geometry. The Cu(I) ion is coordinated by two phenanthroline ligands ...[more]

PMID: 24454185

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