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1-(3-Oxo-3-phenyl-prop-yl)piperidinium chloride.

ABSTRACT: In the title salt, C14H20NO(+)·Cl(-), the piperidine ring adopts a chair conformation. In the crystal, the cations and anions are linked by classical N-H?Cl hydrogen bond and weak C-H?Cl and C-H?O hydrogen bonds; the C-H?O hydrogen bonds exhibit R 2 (2)(14) ring motifs while the C-H?Cl hydrogen bonds link the mol-ecules into chains along the a-axis direction. ?-? stacking is observed between parallel phenyl rings of adjacent cations, the centroid-centroid distance being 3.8164?(15)?Å.

SUBMITTER: Anuradha V

PROVIDER: S-EPMC3885028 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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1-(3-Oxo-3-phenyl-prop-yl)piperidinium chloride.

Anuradha Venkatramu V Madan Kumar S S Siddaraju B P BP Lokanath N K NK Nagendra P P

Acta crystallographica. Section E, Structure reports online 20131106 Pt 12

In the title salt, C14H20NO(+)·Cl(-), the piperidine ring adopts a chair conformation. In the crystal, the cations and anions are linked by classical N-H⋯Cl hydrogen bond and weak C-H⋯Cl and C-H⋯O hydrogen bonds; the C-H⋯O hydrogen bonds exhibit R 2 (2)(14) ring motifs while the C-H⋯Cl hydrogen bonds link the mol-ecules into chains along the a-axis direction. π-π stacking is observed between parallel phenyl rings of adjacent cations, the centroid-centroid distance being 3.8164 (15) Å. ...[more]

PMID: 24454203

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