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(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl-sulfan-yl)propan-2-yl]-2-(thio-phen-2-yl)-1H-imidazole.

ABSTRACT: In the title compound, C34H28N2S2, the central imidazole ring (r.m.s. deviation = 0.0015?Å) forms dihedral angles of 55.7?(3), 17.94?(11) and 86.27?(11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupancy ratio = 0.647?(2):0.353?(2)]. The chiral centre maintains the S configuration of the l-phenyl-alaninol starting material. Intra- and inter-molecular C-H?S hydrogen bonds involving the disordered thienyl ring are observed.

SUBMITTER: Gao J

PROVIDER: S-EPMC3885095 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl-sulfan-yl)propan-2-yl]-2-(thio-phen-2-yl)-1H-imidazole.

Gao Jie J Wang Hongyan H Yang Liangru L Xiao Yongmei Y Mao Pu P

Acta crystallographica. Section E, Structure reports online 20131130 Pt 12

In the title compound, C34H28N2S2, the central imidazole ring (r.m.s. deviation = 0.0015 Å) forms dihedral angles of 55.7 (3), 17.94 (11) and 86.27 (11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupancy ratio = 0.647 (2):0.353 (2)]. The chiral centre maintains the S configuration of the l-phenyl-alaninol starting material. Intra- and inter-molecular C-H⋯S hydrogen bonds involving the disordered thienyl r ...[more]

PMID: 24454271

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