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2,6-Bis(bromo-meth-yl)pyridine.


ABSTRACT: In the title mol-ecule, C7H7Br2N, the C-Br vectors of the bromo-methyl groups extend to opposite sides of the pyridine ring and are oriented nearly perpendicular to its plane. In the crystal, the mol-ecules related by a c-glide-plane operation are arranged into stacks along the c axis, with centroid-centroid distances between neighboring aromatic rings of 3.778?(2)?Å. A short Br?Br contact of 3.6025?(11)?Å is observed within a pair of inversion-related mol-ecules.

SUBMITTER: Cuzan O 

PROVIDER: S-EPMC3914046 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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2,6-Bis(bromo-meth-yl)pyridine.

Cuzan Olesea O   Straistari Tatiana T   Turta Constantin C   Réglier Marius M  

Acta crystallographica. Section E, Structure reports online 20131204 Pt 1


In the title mol-ecule, C7H7Br2N, the C-Br vectors of the bromo-methyl groups extend to opposite sides of the pyridine ring and are oriented nearly perpendicular to its plane. In the crystal, the mol-ecules related by a c-glide-plane operation are arranged into stacks along the c axis, with centroid-centroid distances between neighboring aromatic rings of 3.778 (2) Å. A short Br⋯Br contact of 3.6025 (11) Å is observed within a pair of inversion-related mol-ecules. ...[more]

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