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(E)-2-Methyl-3-phenyl-selanyl-4-(phenyl-sulfin-yl)oct-3-en-2-ol.

ABSTRACT: In the title compound, C21H26O2SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intra-molecular C-H?O hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O-H?O=S hydrogen bonds, generating R 2 (2)(14) loops. Weak C-H?O inter-actions also occur.

SUBMITTER: Wu J

PROVIDER: S-EPMC3914049 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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(E)-2-Methyl-3-phenyl-selanyl-4-(phenyl-sulfin-yl)oct-3-en-2-ol.

Wu Jinglan J Chen Chen C

Acta crystallographica. Section E, Structure reports online 20131204 Pt 1

In the title compound, C21H26O2SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intra-molecular C-H⋯O hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O-H⋯O=S hydrogen bonds, generating R 2 (2)(14) loops. Weak C-H⋯O inter-actions also occur. ...[more]

PMID: 24527011

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