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Trans-Di-chlorido-bis-(pyridazine-?N)palladium(II).

ABSTRACT: The title compound, [PdCl2(C4H4N2)2], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle between the ring plane and Pd-Cl bond is almost perpendicular [89.4?(1)°], while the other is tilted with an angle of 60.0?(1)°. In the crystal, weak C?H-N hydrogen bonds and C?H-Cl inter-actions connect the two independent complex mol-ecules.

SUBMITTER: Laramee B

PROVIDER: S-EPMC3914053 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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trans-Di-chlorido-bis-(pyridazine-κN)palladium(II).

Laramée Baptiste B Hanan Garry S GS

Acta crystallographica. Section E, Structure reports online 20131214 Pt 1

The title compound, [PdCl2(C4H4N2)2], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle between the ring plane and Pd-Cl bond is almost perpendicular [89.4 (1)°], while the other is tilted with an angle of 60.0 (1)°. In the crystal, weak C⋯H-N hydrogen bonds and C⋯H-Cl inter-actions ...[more]

PMID: 24526945

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