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Bis(?2-benzoato-?(2) O:O')bis-[(benzoato-?(2) O,O')bis(4,4'-bi-pyridine-?N)cobalt(II)]-benzoic acid (1/6).

ABSTRACT: In the title compound, [Co2(C7H5O2)4(C10H8N2)4]·6C6H5COOH, the centrosymmetric cobalt dimer co-crystallizes with six mol-ecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4'-bipyridyl ligands are 25.2?(2) and 22.8?(2)°. In the crystal, the three-dimensional network is assembled by O-H?O and C-H?O hydrogen bonds.

SUBMITTER: Pena-Rodriguez R

PROVIDER: S-EPMC3914056 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Bis(μ2-benzoato-κ(2) O:O')bis-[(benzoato-κ(2) O,O')bis(4,4'-bi-pyridine-κN)cobalt(II)]-benzoic acid (1/6).

Peña-Rodríguez Rodolfo R Rivera José María JM Colorado-Peralta Raúl R Duarte-Hernández Angélica María AM Flores-Parra Angelina A

Acta crystallographica. Section E, Structure reports online 20131218 Pt 1

In the title compound, [Co2(C7H5O2)4(C10H8N2)4]·6C6H5COOH, the centrosymmetric cobalt dimer co-crystallizes with six mol-ecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4'-bipyridyl ligands are 25.2 (2) and 22.8 (2)°. In the crystal, the three-dimensional network is assembled by O-H⋯O and C-H⋯O hydrogen bonds. ...[more]

PMID: 24526949

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