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2-(4-Fluoro-phen-yl)-4-(thio-phen-2-yl)-2,3-di-hydro-1,5-benzothia-zepine.

ABSTRACT: In the title compound, C19H14FNS2, the seven-membered thia-zepine ring adopts a slightly distorted twist boat conformation. The dihedral angle between the benzene rings is 53.6?(1)°. The mean plane of the thia-zepine ring is twisted by 34.3?(7)° and 36.6?(7)° from the benezene rings. A C-H?F interaction generates stacking of molecules along the ab plane.

SUBMITTER: Manjula M

PROVIDER: S-EPMC3919547 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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2-(4-Fluoro-phen-yl)-4-(thio-phen-2-yl)-2,3-di-hydro-1,5-benzothia-zepine.

Manjula M M Manjunath B C BC Renuka N N Ajay Kumar K K Lokanath N K NK

Acta crystallographica. Section E, Structure reports online 20131005 Pt 11

In the title compound, C19H14FNS2, the seven-membered thia-zepine ring adopts a slightly distorted twist boat conformation. The dihedral angle between the benzene rings is 53.6 (1)°. The mean plane of the thia-zepine ring is twisted by 34.3 (7)° and 36.6 (7)° from the benezene rings. A C-H⋯F interaction generates stacking of molecules along the ab plane. ...[more]

PMID: 24526934

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