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A cope rearrangement-based route to hexahydroazulenes.

ABSTRACT: 2-exo-Vinyl-7-alkylidenenorbornanes, readily prepared from fulvene Diels-Alder adducts, undergo smooth Cope rearrangement at elevated temperatures to produce hexahydroazulene derivatives.

SUBMITTER: Seizert CA

PROVIDER: S-EPMC3947830 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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A cope rearrangement-based route to hexahydroazulenes.

Seizert Curtis A CA Bumbu Valentina D VD Birman Vladimir B VB

Organic letters 20100801 15

2-exo-Vinyl-7-alkylidenenorbornanes, readily prepared from fulvene Diels-Alder adducts, undergo smooth Cope rearrangement at elevated temperatures to produce hexahydroazulene derivatives. ...[more]

PMID: 20586456

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