Ontology highlight
ABSTRACT:
SUBMITTER: Bi B
PROVIDER: S-EPMC3947835 | biostudies-literature | 2011 Nov
REPOSITORIES: biostudies-literature
Bi Bo B Huang Richard Y-C RY Maurer Karl K Chen Ceng C Moeller Kevin D KD
The Journal of organic chemistry 20111010 21
A "safety-catch" linker strategy has been used to release a portion of the products of a Diels-Alder reaction conducted on a microelectrode array for characterization of stereochemistry. The attachment and cleavage of organic compounds from the surface of selected electrodes in the array can be accomplished by site-selective generation of base or acid at the electrode. It was found that the surface of the array had a minor influence on the stereochemistry of the Diels-Alder reaction, leading to ...[more]