Amplification of the stereochemistry of biomolecular adsorbates by deracemization of chiral domains in bent-core liquid crystals.
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ABSTRACT:
SUBMITTER: Lee G
PROVIDER: S-EPMC3963425 | biostudies-literature | 2013 Jan
REPOSITORIES: biostudies-literature
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Amplification of the stereochemistry of biomolecular adsorbates by deracemization of chiral domains in bent-core liquid crystals.
Lee Guksik G Carlton Rebecca J RJ Araoka Fumito F Abbott Nicholas L NL Takezoe Hideo H
Advanced materials (Deerfield Beach, Fla.) 20121026 2
Assemblies of chiral phospholipids that form spontaneously at interfaces between aqueous phases and bent-core liquid crystals can deracemize mixtures of chiral domains that otherwise form in the liquid crystal phase. An enantiomeric excess of chiral domains is induced by adsorption of either L- or D-phospholipid with the same sense of optical rotation. ...[more]
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