Nanosponge formation from organocatalytically-synthesized poly(carbonate) copoplymers.
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ABSTRACT:
SUBMITTER: Stevens DM
PROVIDER: S-EPMC3979553 | biostudies-literature | 2012 Jul
REPOSITORIES: biostudies-literature
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Nanosponge formation from organocatalytically-synthesized poly(carbonate) copoplymers.
Stevens David M DM Tempelaar Sarah S Dove Andrew P AP Harth Eva E
ACS macro letters 20120701 7
Advanced organocatalytic synthesis methods were employed to prepare linear poly(carbonate)s with control over functional group incorporation and molecular weight. Pendant allyl or epoxide groups served as reaction partners in thiol-ene click or epoxide-amine reactions with ethylene oxide-containing crosslinking groups to form a panel of six novel poly(carbonate) nanosponges with crosslinking densities ranging from 5%, 10% and 20% <i>via</i> an intermolecular chain-crosslinking approach. ...[more]
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