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Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins.


ABSTRACT: A highly efficient palladium-catalyzed decarbonylative dehydration reaction of carboxylic acids is reported. This method transforms abundant and renewable even-numbered natural fatty acids into valuable and expensive odd-numbered alpha olefins. Additionally, the chemistry displays a high functional group tolerance. The process employs low loading of palladium catalyst and proceeds under solvent-free and relatively mild conditions.

SUBMITTER: Liu Y 

PROVIDER: S-EPMC3998208 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins.

Liu Yiyang Y   Kim Kelly E KE   Herbert Myles B MB   Fedorov Alexey A   Grubbs Robert H RH   Stoltz Brian M BM  

Advanced synthesis & catalysis 20140101 1


A highly efficient palladium-catalyzed decarbonylative dehydration reaction of carboxylic acids is reported. This method transforms abundant and renewable even-numbered natural fatty acids into valuable and expensive odd-numbered alpha olefins. Additionally, the chemistry displays a high functional group tolerance. The process employs low loading of palladium catalyst and proceeds under solvent-free and relatively mild conditions. ...[more]

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