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Tetra-chloridodi-?3-oxido-tetra-kis-(?2-propan-2-olato-?(2) O:O)ditin(II)ditin(IV).

ABSTRACT: The centrosymmetric tetranuclear title molecule, [Sn4(C3H7O)4Cl4O2], contains two types of Sn atoms, Sn(II) and Sn(IV). The Sn(II) atom has a trigonal-pyramidal coordination environment and is bonded to two O atoms from two iso-propano-late groups and one ?3-oxide atom. The Sn(IV) atom has an octa-hedral coordination environment, formed by two chloride atoms, two ?3-oxide atoms and two O atoms from iso-propano-late groups.

SUBMITTER: Yarushnikov O

PROVIDER: S-EPMC3998255 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Tetra-chloridodi-μ3-oxido-tetra-kis-(μ2-propan-2-olato-κ(2) O:O)ditin(II)ditin(IV).

Yarushnikov Oleg O Naumova Dina D Klishin Nikolai N Rusanov Eduard E Brusylovets Oleksii O

Acta crystallographica. Section E, Structure reports online 20140118 Pt 2

The centrosymmetric tetranuclear title molecule, [Sn4(C3H7O)4Cl4O2], contains two types of Sn atoms, Sn(II) and Sn(IV). The Sn(II) atom has a trigonal-pyramidal coordination environment and is bonded to two O atoms from two iso-propano-late groups and one μ3-oxide atom. The Sn(IV) atom has an octa-hedral coordination environment, formed by two chloride atoms, two μ3-oxide atoms and two O atoms from iso-propano-late groups. ...[more]

PMID: 24764816

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