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Tetra-kis[bis-(pyridin-2-yl)amine-?N (2)](nitrato-?O)silver(I).

ABSTRACT: In the title complex, [Ag(NO3)(C10H9N3)4], the nitrate ligand is found to be disordered over two sets of positions, with occupancy factors of 0.473?(5) and 0.527?(5). The Ag(I) ion is located in a square-pyramidal coordination environment formed by four N atoms from four bis-(pyridin-2-yl)amine ligands and one O atom from a nitrate ligand. Weak inter-actions between the Ag(I) ions and the nitrate anions acting in a monodentate mode [Ag?O = 2.791?(13) and 2.816?(9)?Å for the major component of the nitrate ligand, and 2.865?(8) and 2.837?(8)?Å for the minor component] link the complex mol-ecules into a chain along [001]. N-H?O hydrogen bonds are observed.

SUBMITTER: Parashchenko Y

PROVIDER: S-EPMC3998263 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Tetra-kis[bis-(pyridin-2-yl)amine-κN (2)](nitrato-κO)silver(I).

Parashchenko Yuliia Y Pavlishchuk Anna A Bokach Nadezhda A NA Haukka Matti M

Acta crystallographica. Section E, Structure reports online 20140122 Pt 2

In the title complex, [Ag(NO3)(C10H9N3)4], the nitrate ligand is found to be disordered over two sets of positions, with occupancy factors of 0.473 (5) and 0.527 (5). The Ag(I) ion is located in a square-pyramidal coordination environment formed by four N atoms from four bis-(pyridin-2-yl)amine ligands and one O atom from a nitrate ligand. Weak inter-actions between the Ag(I) ions and the nitrate anions acting in a monodentate mode [Ag⋯O = 2.791 (13) and 2.816 (9) Å for the major component of th ...[more]

PMID: 24764824

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