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[1H-1,2,4-Triazole-5(4H)-thione-?S]bis-(tri-phenyl-phosphane-?P)(nitrato-?O)silver(I) methanol monosolvate.

ABSTRACT: In the title complex, [Ag(NO3)(C2H3N3S)(C18H15P)2]·CH3OH, the Ag(I) ion exhibits a distorted tetra-hedral coordination geometry formed by two P atoms from two tri-phenyl-phosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent mol-ecules are linked by O-H?O and N-H?O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C-H?O hydrogen bonds forming a two-dimensional supra-molecular architecture parallel to (001). In addition, an intra-molecular N-H?O hydrogen bond is observed.

SUBMITTER: Wattanakanjana Y

PROVIDER: S-EPMC3998265 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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[1H-1,2,4-Triazole-5(4H)-thione-κS]bis-(tri-phenyl-phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate.

Wattanakanjana Yupa Y Palamae Sureeporn S Ratthiwan Jenejira J Nimthong Ruthairat R

Acta crystallographica. Section E, Structure reports online 20140122 Pt 2

In the title complex, [Ag(NO3)(C2H3N3S)(C18H15P)2]·CH3OH, the Ag(I) ion exhibits a distorted tetra-hedral coordination geometry formed by two P atoms from two tri-phenyl-phosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C-H⋯O hydrogen bonds forming a two-dimensional supra-m ...[more]

PMID: 24764826

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