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Bis(n-do-decyl-ammonium) bis-(chlor-anil-ato)di-ethano-lcuprate(II).

ABSTRACT: In the title compound, (C12H25NH3)2[Cu(C6Cl2O4)2(C2H5OH)2], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa-hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol-ecules which are trans to each other in the axial positions. In the crystal, the Cu(II) mononuclear dianions are linked by O-H?O hydrogen bonds into a tape along the a-axis direction. The tapes are linked through N-H?O hydrogen bonds between the dianion and the n-do-decyl-ammonium cation, forming a two-dimensional network parallel to the ab plane.

SUBMITTER: Himegi A

PROVIDER: S-EPMC3998266 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Bis(n-do-decyl-ammonium) bis-(chlor-anil-ato)di-ethano-lcuprate(II).

Himegi Akiko A Kawata Satoshi S

Acta crystallographica. Section E, Structure reports online 20140122 Pt 2

In the title compound, (C12H25NH3)2[Cu(C6Cl2O4)2(C2H5OH)2], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa-hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol-ecules which are trans to each other in the axial positions. In the crystal, the Cu(II) mononuclear dianions are linked by O-H⋯O hydrogen bonds into a tape along the a-axis direction. The tapes are linked through N-H⋯O hydrogen bonds between the ...[more]

PMID: 24764827

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